曾宪顺，1969年4月，天津理工大学材料科学与工程学院博导，硕导，研究员


研究方向
0805材料科学与工程（03生物医用材料） 1） 有机小分子荧光探针/荧光成像；2） 有机组装体/超分子器件
人才称号
教育部新世纪优秀人才支持计划人选 ；天津市“131”创新型人才培养工程第一层次人选 ；
学术兼职
哈尔滨工业大学外聘博导,《功能材料》编委
讲授课程
分子信息材料；近代分析测试技术；
主要科研项目及代表性成果(包括鉴定项目、论文、专著、获奖、专利等)：
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1.         and selective turn-on fluorescent chemosensor for palladium based on a phosphine-rhodamine conjugate, Chem. Commun., 2013, 49, 822-824.

2.         Liu C., Lu Y., He S., Wang Q., Zhao L., Zeng X., The nature of the styrylindolium dye: transformations among monomer, aggregates and water adducts and its photophysical properties, J. Mater. Chem. C. 2013, 1, 4770-4778.

3.         Wang Q., Liu C., Lu Y., He S., Liu C., Zhao L., Zeng X., Novel Water Soluble Styrylquinolinium Boronic Acid as a Ratiometric Reagent for the Rapid Detection of Hypochlorite, Dyes and Pigments, 2013, 99, 733-739.

4.         Li Y., He S., Lu Y., L. Zhao, Zeng X., Novel mercury sensor based on water soluble styrylindolium Dye, Dyes and Pigments, 2013, 96, 424-429.

5.         Over D., Zeng X., Bornholdt C., Marrot J., Reinaud O., Coordination of Lead(II) in the Supramolecular Environment Provided by a “Two-Story” Calix[6]arene-based N6 Ligand. Inorg. Chem., 2013, 52, 14089-14095

6.         Sun J., Lu Y., Wang L., Cheng D., Sun Y., Zeng X., Fluorescence turn-on detection of DNA based on the aggregation-induced emission of conjugated poly(pyridinium salt)s, Polym. Chem., 2013, 4, 4045-4051.

7.         Wei F., Lu Y., He S., Zhao L., Zeng X., Highly Sensitive Fluorescent Chemosensor for Hypochlorite Anion Based on a Novel Irreversible Ring-Opened Strategy, Anal. Methods, 2012, 4, 616-618.

8.         Wei F., Lu Y., He S., Zhao L., Zeng X., Selective and sensitive fluorescence chemosensor for the hypochlorite anion in water, J. Fluoresc. 2012, 22, 1257–1262.

9.         Han F., Lu Y., Zhang Q., Sun J., Zeng X., Li C., Homogeneous and sensitive DNA detection based on polyelectrolyte complexes of cationic conjugated poly(pyridinium salt)s and DNA, J. Mater. Chem., 2012, 22, 4106-4112.

10.     王炜 何松 陆燕 曾宪顺，基于杯[4]芳烃的银离子荧光探针合成与性能，高等学校化学学报，2012，33，2470-2475

11.     Lu Y., Huang S., Liu Y., He S., Zhao L. and Zeng X., Highly Selective and Sensitive Fluorescent Turn-on Chemosensor for Al3+ Based on a Novel Photoinduced Electron Transfer Approach, Org. Lett. 2011, 13, 5274-5277.

12.     Huang S., He S., Lu Y., Wei F., Zeng X. and Zhao L., Highly sensitive and selective fluorescent chemosensor for Ag+ based on a coumarin-Se2N chelating conjugate, Chem. Commun. 2011, 47, 2408-2410.

13.     Zeng X., Bornholdt C., Over D., Reinaud O., Synthesis of “Two-Story” Calix[6]aza-Cryptands, Org. Lett. 2011, 13, 5660-5663.

14.     Li Y., He S., Lu Y., Zeng X., Novel Hemicyanine Dye as Colorimetric and Fluorometric Dual-modal Chemosensor for Mercury in Water, Org. Biomol. Chem. 2011, 9, 2606-2609.

15.     何松，陆阳，李园园，陆燕，曾宪顺，基于C3v对称性的杯[6]芳烃对Hg2+的荧光选择性识别行为，高等学校化学学报, 2011, 32, 2139-2144.

16.     李园园, 陆燕, 何松, 曾宪顺， 基于半青蓝素修饰的汞离子探针比色传感行为研究，高等学校化学学报, 2011, 32, 2123-2127.

17.     Ren Y., Li C., Lu Y., Wang X., Zeng X. Aggregates of cholic acid and benzylamine as templates for the formation of hollow silica spheres, J. Mater. Sci. 2010, 45, 6830–6833.

18.     Zeng X., Wang C., Batsanov A. S., Bryce M. R., Gigon J., Urasinska-Wojcik B., Ashwel G. J., Synthesis and Properties of Functionalized Oligo(arylene) Molecular Wires with Thiolated Termini: Competing Thiol-Au and Nitro-Au Assembly, J. Org. Chem. 2010, 75, 139-136.

19.     Lu Y., Li Y., He S., Lu Y., Liu C., Zeng X., Chen L.,   Synthesis and properties of calix[4]arene telluropodant ethers as Ag+ selective sensors and Ag+, Hg2+ extractants, Beilstein J. Org. Chem. 2009, 5: 59.

20.     Lu Y., Xiao C., Yu Z., Zeng X., Ren Y., Li C., Poly(pyridinium) salts containing calix[4]arene segments in the main chain as potential biosensors, J. Mater. Chem. 2009, 19, 8796-8802.

21.     Liu L., Li X., Hou S., Xue Y., Yao Y., Ma Y., Feng X., He S., Lu Y., Wang Y., Zeng X. Nanoparticles from Block Copolymer Encapsulating Re(phen) complexes as Bifunctional Agents for Cell Imaging and Gene Transfection, Chem. Commun. 2009, 6759-6761.

22.     Over O., Douziech B., de Lalande A., Zeng X., Parisel O., Le Mest Y., Reinaud O. Replacement of a nitrogen by a phosphorous donor in biomimetic copper complexes: a surprising but informative case study with calix[6]arene-based cryptands, Inorg. Chem. 2009, 48, 4317-4330.

23.     Rothe C., Chiang C.-J., Jankus V., Abdullah K., Zeng X., Jitchati R., Batsanov A. S., Bryce M. R., Monkman A. P. Ionic Iridium(III) Complexes with Bulky Side Groups for Use in Light Emitting Cells (LECs) Reduction of Concentration Quenching, Adv. Funct. Mater. 2009, 19, 2038-2044.

24.     Zeng X., Tavasli M., Perepichka I. F., Batsanov A. S., Bryce M. R., Chiang C.-J., Rothe C., Monkman A. P., Cationic Bis-cyclometalated Iridium(III) Phenanthroline Complexes with Pendant Fluorenyl Substituents: Synthesis, Redox, Photophysical Properties and Light-Emitting Cells, Chem. Eur. J. 2008, 14, 933-943.

25.     Zeng X., Wang C., Bryce M. R., Batsanov A. S., Sirichantaropass S., Garcia-Suarez V. M., Lambert C. J., Sage I., Functionalized 8 nm Long Aryleneethynylene Molecular Wire with Alkyne Termini, Eur. J. Org. Chem. 2007, 5244-5249.

26.     Qin D., Zeng X., Li Q., Xu F., Song H., Zhang Z.-Z., Silver(I) N-Heterocyclic Carbene-Bridged Calix[4]arene Analogues as Efficient [60]Fullerene Receptor, Chem. Commun. 2007, 147-149.

27.     Barker C. A., Zeng X., Bettington S., Batsanov A. S., Bryce M. R., Beeby A., Porphyrin, Phthalocyanine and Porphyrazine Derivatives with Multifluorenyl Substituents as Efficient Deep-Red Emitters, Chem. Eur. J. 2007, 13, 6710 -6717.

28.     Izzet G., Zeng X., Akdas H., Marrot J., Reinaud O., Drastic effects of the second coordination sphere on neutral vs. anionic guest binding to a biomimetic Cu(II) center embedded in a calix[6]azacryptand, Chem. Commun. 2007, 810-812.

29.     Izzet G., Zeng X., Over D., Giorgi M., Jabin I., Le Mest Y., Reinaud O., First insights into the electronic properties of a Cu(II) center embedded in the PN3 cap of a calix[6]arene-based ligand. Inorg. Chem. 2007, 46, 375-377.

30.     Zeng X., Batsanov S. A., Bryce M. R. Calix[6]arene Derivatives Selectively Functionalis-ed at Alternate Sites on the Smaller Rim with 2-Phenylpyridine and 2-Fluorenylpyridine Substituents to Provide Deep Cavities, J. Org. Chem. 2006, 71, 9589-9594.

31.     Le Gac S., Zeng X., Girardot C., Jabin I., Efficient Syntheses and Host-guest Properties of Two New Calix[6]aza-cryptands, J. Org. Chem. 2006, 71, 9233-9236.

32.     Zeng X., Coquiere, D., Alenda, A., Garrier, E., Prangé, T., Li, Y., Reinaud O., Jabin, I., Efficient Synthesis of Calix[6]tmpa: a New Calix[6]aza-cryptand with Original Conformational and Host-Guest Properties. Chem. Eur. J. 2006, 12, 6393-6402.

33.     Qin D., Zeng X., Liu C., Xu F., Li Q., Zhang Z., Mercury Selective Extraction by Novel Macrocyclic Calix[4](diseleno)crown-5 Ethers, Chin. J. Chem. 2006, 24, 674-680.

34.     Darbost U., Zeng X., Giorgi M., Jabin I.: Optically Pure Calix[6]trisammoniums: Syntheses and Host-guest Properties toward Neutral Guests, J. Org. Chem. 2005, 70, 10552-10560.

35.     卢春阳，王华芳，何锡文，陈朗星，李文友，曾宪顺，张玉奎，杯芳烃衍生物和丙稀酰胺作为复合功能单体的分子印迹聚合物对海因类化合物的选择性识别研究，高等学校化学学报，2005, 26, 1820-1824。

36.     吕鉴泉, 曾宪顺, 艾娟, 庞代文, 钳状杯[4]芳烃为探针的固态PVC膜汞离子选择性电极,高等学校化学学报, 2005, 26, 238-240.

37.     Le Gac S., Zeng X., Reinaud O., Jabin I. Synthesis and Conformational Study of the First Triply Bridged Calix[6]azatubes, J. Org. Chem. 2005, 70, 1204-1210.

38.     Darbost U., Zeng X., Rager M.-N., Giorgi M., Jabin I., Reinaud O., X-ray and Solution Structure of the First Zn Funnel Complex Based on a Calix[6]aza-cryptand. Eur. J. Inorg. Chem. 2004, 4371-4374.

39.     Zeng X., Hucher, H., Reinaud O., Jabin, I.: A Novel Receptor Based on a C3v-Symmetrical PN3-calix[6]cryptand, J. Org. Chem. 2004, 69, 6886-6889.

40.     Liu C., Qing D., Leng X., Chen L., Zeng X., Xu F., Li Q., He X., Zhang, W., Zhang Z., Influences of Hard Donor on Cation Selectivities Closing to Soft Selenium Donor in Tweezer-like Calix[4]arene Receptors, Chin. J. Chem. 2004, 22, 804-810.

41.     Lu J., Pang D., Zeng X., He X., A new solid-state silver ion-selective electrode based on a novel tweezer-type calixarene derivative. J. Electroanal. Chem. 2004, 568, 37-43.

42.     Lu C., He H., He X., Zeng X., Molecularly Imprinted Polymer with Calix[4]arene Derivative for the Recognition of Acetanilide. Chin. J. Chem. 2004, 22, 275-278.

43.     Xu F., Li Q., Zeng X., Leng X., Zhang Z., Bimetallocyclophanes Formed by the π- Stacking Interaction Approach and Fluorescent Chemosensing Behavior. Organometallics, 2004, 23, 632-634.

44.     荻晓威， 何锡文，曾宪顺，邹本东，硒功能化杯芳烃载体银离子选择性膜电极的研究，分析化学，2004，32, 430-434.

45.     Cui D., Zhao Y., Zeng X., Xu F., Leng X., Li Q., Zhang Z., Synthesis and crystal structure of Mo(CO)4(NNP) (NNP=2-(N-cyclohexyl-N- diphenylphosphinomethyl)aminopyridine). Jiegou Huaxue, 2003, 22, 297-300.

46.     Li Q., Xu F., Cui D., Yu K., Zeng X., Leng X., Song H., Zhang Z., Heterobimetallic Pt(ii)-M(i) (M = Cu, Ag) eight-membered macrocyclic complexes with large-bite P,N-ligand bridges. Dalton Transactions, 2003, 1551-1557.

47.     Zeng X., Sun H., Chen L., Leng X., Xu F., Li Q., He X., Zhang W., Zhang Z. -Z. Synthesis of a tweezer-like bis(arylthiaalkoxy)calix[4]arene as a cation sensor for ion-selective electrodes: an investigation of the influence of neighboring halogen atoms on cation selectivity. Org. Biomol. Chem. 2003, 1, 1073-1079.

48.     荻晓威，何锡文，曾宪顺，硒功能化杯[4]芳烃对金属离子的识别及在PVC基质支撑液膜的传输作用，化学学报，2003, 61, 1854-1859.

49.     Cui D. Peng L. Zeng X., Xu F., Zhang Z. New substitution process for preparation of trans-Fe(CO)(3) (PR3)(2), Chin. J. Org. Chem. 2003, 23, 973-976

50.     Liu Q., Song H., Xu F., Li Q., Zeng X., Leng X., Zhang Z., Formation and crystal structures of 9-methylanthracene photodimer and iepidopterene. J. Chem. Res. (S), 2003, 445-447.

51.     Lu J., He X., Zeng X., Zhang H., Zhang Z., Anodic stripping voltammetric determination of lead(II) using glassy carbon electrode modified with novel calix[4]arene. Chin. J. Chem. 2003, 21, 687-692.

52.     Cui D. J., Zeng X., Leng X., Xu F., Zhang Z., trans-Tricarbonylbis[diphenyl(benzoylmethyl)- phos-phine]iron(0). Acta Crystal. E. 2003, E59, m546-m547.

53.     Cui D. J., Zeng X., Leng X., Xu F., Zhang Z., An unexpected product: di-η-iodo-bis{[2-(N-diphenyl-phosphinomethyl- N-cyclohexylamino)pyridine]iodomercury(II)}. Acta Crystal. E. 2003, E59, o868-o869.

54.     Liu Q., Song H., Xu F., Li Q., Zeng X., Leng X., Zhang Z., Synthesis, crystal structure and photophysical properties of N-heterocyclic carbene Pd(II), Pt(II) complexes and iodine adduct. Polyhedron, 2003, 22, 1515-1521. 53.

55.     Cui D., Zeng X., Leng X., Xu F., Zhang Z., {[N-Benzyl-N-(2-pyridyl)amino]methylene} diphenyl- phosphine oxide. Acta Crystal. E. 2003, E59, o679-o680.

56.     吕鉴泉, 何锡文, 曾宪顺, 万其进, 张正之, 新型钳状芳杂环杯[4]芳烃修饰电极对银离子的分子识别研究, 高等学校化学学报, 2003, 24, 398-403.

57.     Lu J., He X., Zeng X., Wan Q., Zhang Z., Voltammetric determination of mercury(II) in aqueous media using glassy carbon electrodes modified with novel calix[4]arene. Talanta, 2003, 59, 553-560.

58.     Xu F., Li Q., Wu L., Leng X., Li Z., Zeng X., Chow Y., Zhang Z., Formation of Group 11 Metal(I)-Arene Complexes: Bonding Mode and Molecule-Responsive Spectral Variations. Organometallics, 2003, 22, 633-640.

59.     陈朗星，张佳，何锡文，曾宪顺，张正之，杯芳烃衍生物液-液萃取和液膜传输银的对比研究及机理探讨，化学学报, 2003, 61, 104-109.

60.     Liu Q., Xu F., Li Q., Zeng X., Leng X., Chou Y., Zhang Z., A Luminescent Silver(I) Carbene Stair Polymer. Organometallics, 2003, 22, 309-314.

61.     Zeng X., Leng X., Chen L., Sun H., Xu F., Li Q., He X., Zhang Z., Novel bis(phenylseleno- alkoxy)calix[4]arene molecular tweezer receptors as sensors for ion-selective electrodes. J. Chem. Soc., Perkin Trans. 2, 2002, 796-801.

62.     Xu F., Li Q., Zeng X., Leng X., Zhang Z., The Calix-Shaped Metallocyclophane [Rh{9,10-bis(2- (diphenylphosphino)ethyl) anthracene}(CO)Cl]3 and Its Solution Behavior. Organometallics, 2002, 21, 4894-4896.

63.     Sun H., Zeng X., Lu J., Leng X., Chen Q., Xu F., Li Q., He X., Zhang W., Zhang, Z., Synthesis of a   enhanced sensorptweezer-like bis(phenylthiapropoxy) calix[4]arene as a cation/π for ion-selective electrodes. Chin. J. Chem., 2002, 20, 1109-1114.

64.     Liu Q., Xu F., Li Q., Zeng X., Leng X., Zhang Z., Preparation, structural characterization and luminescent property of binuclear silver(I) complex formed by benzotriazole and 1-hydroxymethylbenzotriazole. Chin. J. Chem., 2002, 20, 878-883.

65.     Zeng X., Weng L., Chen L., Xu F., Li Q., Leng X., He X., Zhang Z. The syntheses and Ag+-selective electrode properties of benzothiazolylthiaalkoxy functionalized calix[4]arenes: an investigation of the structure-selectivity relationship in the ionophore-based ISEs. Tetrahedron, 2002, 58, 2647-2658.

66.     Zeng X., Han X., Chen L., Li Q., Xu F., He X., Zhang Z. -Z. The first synthesis of a calix[4](diseleno)crown ether as a sensor for ion-selective electrodes. Tetrahedron Lett., 2002, 43, 131-134.

67.     Chen L., Ju H., Zeng X., He X., Zhang Z., Cesium selective electrodes based on novel double flexible spacers bridged biscalix[4]arenes. Anal. Chim. Acta, 2001, 447, 41-46.

68.     Chen L., Ju H., Zeng X., He X., Zhang Z., Silver ion-selective electrodes based on novel containing benzothiazolyl calix[4]arene. Anal. Chim. Acta, 2001, 437, 191-197.

69.     Zeng X., Weng L., Zhang Z., The first lower-rim O-arylation of calix[4]arenes. Chem. Lett., 2001, 550-551.

70.     Zeng X., Weng L., Chen L., Ju H., Leng X., He X., Zhang Z., Synthesis and structure of novel double flexible spacer bridged biscalix[4]arenes. Chin. J. Chem., 2001, 19, 493-499.

71.     Zeng X., Weng L., Chen L., Leng X., Ju H., He X., Zhang Z., The synthesis of some pyridyl functionalized calix[4]arenes as the sensor molecule for silver ion-selective electrodes. J. Chem. Soc., Perkin Trans. 2, 2001, 545-549.

72.     Zeng X., Chen L., Weng L., Ju H., He X., Zhang Z., Syntheses and ion-selective properties of 25,27-bis(2-hydroxyethyl- thioalkoxyl)-26,28-dihydroxycalix[4]arenes. J. Chem. Res. (S), 2000, 518-519.

73.     Chen L., Zeng X., Ju H., He X., Zhang Z., Calixarene derivatives as the sensory molecules for silver ion-selective electrode. Microchem. J., 2000, 65, 129-135.

74.     Chen L., Zeng X., He X., Zhang Z., Selective electrodes for silver based on polymeric membranes containing calix[4]arene derivatives. Fresenius J. Anal. Chem., 2000, 367, 535-538.

75.     Zeng X., Weng L., Chen L., Leng X., Zhang Z., He X., Improved silver ion-selective electrodes using novel 1,3-bis(2-benzothiazolyl) thioalkoxy-p-tert-butylcalix[4]arenes. Tetrahedron Lett., 2000, 41, 4917-4921

76.     曾宪顺, 曾强, 崔涛, 汪清民, 李东波, O-(3-三苯锗基)正丙基硫代磷酸酯及类似物的合成, 化学学报, 1999, 57, 196-201.

77.     Zeng Q., Zeng X., Wang Q., Cui T., Zhang Z., Synthesis and reactivity of 3-(trichlorogermyl)-propanoic acid and 3-(triphenylgermyl)propanoic acid. Chin. J. Chem., 1998, 16, 184-192.

 

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